A study of some selected rhodium (II) carboxylates

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dc.contributor.advisorBear, John L.
dc.contributor.committeeMemberWendlandt, Wesley W.
dc.contributor.committeeMemberBecker, Ralph S.
dc.contributor.committeeMemberKimball, Aubrey P.
dc.contributor.committeeMemberWillcott, Mark Robert, III
dc.creatorKitchens, Judith F.
dc.date.accessioned2022-06-22T20:15:27Z
dc.date.available2022-06-22T20:15:27Z
dc.date.issued1969
dc.description.abstractRhodium(II) acetate, propionate, tri fluoroacetate, tri chloroacetate, and benzoate have been prepared and some of their properties studied by thermal, magnetic and spectroscopic methods. The spectra in ERA mixed solvent (diethyl ether, isopentane and ethanol 5:5:2) are shown and compared in order to interpret the results. The properties of the reaction products of rhodium(II) acetate with many donor-type ligands were investigated by thermogravimetric analysis, differential scanning calorimetry, magnetic susceptibility and spectroscopic measurements. A new type of adduct of the formula, Rh[lowered 2](OOCCH[lowered 3)[lowered 4][dot]L, has been isolated and characterized. The "exchange" reaction in which rhodium(II) tri fluoroacetate is formed by the reaction of rhodium(II) acetate with excess tri fluoroacetic acid was studied by nuclear magnetic resonance spectroscopy. The intermediates were identified by mass spectrometry.
dc.description.departmentChemistry, Department of
dc.format.digitalOriginreformatted digital
dc.format.mimetypeapplication/pdf
dc.identifier.other13740313
dc.identifier.urihttps://hdl.handle.net/10657/9914
dc.language.isoen
dc.rightsThis item is protected by copyright but is made available here under a claim of fair use (17 U.S.C. Section 107) for non-profit research and educational purposes. Users of this work assume the responsibility for determining copyright status prior to reusing, publishing, or reproducing this item for purposes other than what is allowed by fair use or other copyright exemptions. Any reuse of this item in excess of fair use or other copyright exemptions requires express permission of the copyright holder.
dc.titleA study of some selected rhodium (II) carboxylates
dc.type.dcmiText
dc.type.genreThesis
thesis.degree.collegeCollege of Arts and Sciences
thesis.degree.departmentChemistry, Department of
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Houston
thesis.degree.levelDoctoral
thesis.degree.nameDoctor of Philosophy

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