Crystal field treatment of high spin cobalt (II) and rhodium (II) complexes in D[lowered 4h] symmetry

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dc.contributor.committeeMemberBear, John L.
dc.contributor.committeeMemberBecker, Ralph S.
dc.contributor.committeeMemberFuchs, Richard
dc.contributor.committeeMemberMcElrath, Eby N.
dc.contributor.committeeMemberKnopp, Paul J.
dc.creatorFahrenthold, Paul David
dc.date.accessioned2022-09-19T20:42:59Z
dc.date.available2022-09-19T20:42:59Z
dc.date.copyright1966
dc.date.issued1966
dc.description.abstractThe determination of the energies of the symmetry states resulting from the application of a crystal, ionic field of D[lowered 4h] symmetry on a metal ion with high spin d[raised 7] configuration has been completed. The energies of the states were determined by operator techniques and are presented in terms of the splitting parameters Ds, Dt, and Dq. The effects of the configuration interaction parameter [delta], the nephelauxetic constant and the many electron spin-orbit coupling parameter [lambda] on the energies of the states were also determined. The crystal field model was applied to a 4d[raised 7] high spin compound, binuclear rhodium (II) acetate, and several 3d[raised 7] high spin complexes. The 3d[raised 7] complexes were those of cobalt (II) with Schiff Base ligands and with trifluoro-, hexafluoro- and unsubstituted acetyl acetone. The values of the parameters which give a reasonable fit to the experimental data are given.
dc.description.departmentChemistry, Department of
dc.format.digitalOriginreformatted digital
dc.format.mimetypeapplication/pdf
dc.identifier.other13726805
dc.identifier.urihttps://hdl.handle.net/10657/11395
dc.language.isoen
dc.rightsThis item is protected by copyright but is made available here under a claim of fair use (17 U.S.C. Section 107) for non-profit research and educational purposes. Users of this work assume the responsibility for determining copyright status prior to reusing, publishing, or reproducing this item for purposes other than what is allowed by fair use or other copyright exemptions. Any reuse of this item in excess of fair use or other copyright exemptions requires express permission of the copyright holder.
dc.titleCrystal field treatment of high spin cobalt (II) and rhodium (II) complexes in D[lowered 4h] symmetry
dc.type.dcmiText
dc.type.genreThesis
dcterms.accessRightsThe full text of this item is not available at this time because it contains documents that are presumed to be under copyright and are accessible only to users who have an active CougarNet ID. This item will continue to be made available through interlibrary loan.
thesis.degree.collegeCollege of Arts and Sciences
thesis.degree.departmentChemistry, Department of
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Houston
thesis.degree.levelDoctoral
thesis.degree.nameDoctor of Philosophy

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