A kinetic study of some ligand substitution reactions

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dc.contributor.advisorBear, John L.
dc.contributor.committeeMemberWendlandt, Wesley W.
dc.contributor.committeeMemberMcElrath, Eby N.
dc.contributor.committeeMemberWhitcomb, Margaret R.
dc.creatorLin, Chin-tung
dc.date.accessioned2022-06-22T20:15:32Z
dc.date.available2022-06-22T20:15:32Z
dc.date.issued1967
dc.description.abstractThe rate constant for the formation and dissociation of the one-to-one complexes of nickel with malonate and succinate ligands and magnesium with oxalate ligand have been determined by a pressure-jump technique. The rates were determined at different temperatures and the activation parameters calculated. The results indicate that within experimental error there is no change in the activation parameters resulting from a change in properties of the ligand and they are consistent with a model in which the rate-determining step is the elimination of a water molecule from the inner hydration shell of the metal ion.
dc.description.departmentChemistry, Department of
dc.format.digitalOriginreformatted digital
dc.format.mimetypeapplication/pdf
dc.identifier.other13740397
dc.identifier.urihttps://hdl.handle.net/10657/9917
dc.language.isoen
dc.rightsThis item is protected by copyright but is made available here under a claim of fair use (17 U.S.C. Section 107) for non-profit research and educational purposes. Users of this work assume the responsibility for determining copyright status prior to reusing, publishing, or reproducing this item for purposes other than what is allowed by fair use or other copyright exemptions. Any reuse of this item in excess of fair use or other copyright exemptions requires express permission of the copyright holder.
dc.titleA kinetic study of some ligand substitution reactions
dc.type.dcmiText
dc.type.genreThesis
thesis.degree.collegeCollege of Arts and Sciences
thesis.degree.departmentChemistry, Department of
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Houston
thesis.degree.levelMasters
thesis.degree.nameMaster of Science

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