1. Reduction of phenylthiomethylcarbinyl benzoate esters to alkenes with titanium metal. 2. Cyclopentenone synthesis via the alkylating agent 1-(chloromethyl) ethenyl diethyl phosphate

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dc.contributor.advisorWelch, Steven C.
dc.contributor.committeeMemberFuchs, Richard
dc.contributor.committeeMemberThummel, Randolph Paul
dc.contributor.committeeMemberAlbright, Thomas A.
dc.contributor.committeeMemberCates, Lindley A.
dc.creatorLoh, Jiann-Ping
dc.date.accessioned2023-12-08T20:57:37Z
dc.date.available2023-12-08T20:57:37Z
dc.date.copyright1983-05
dc.date.issued1983
dc.description.abstractA high yield and simple method for the reduction of phe-nylthiomethylcarbinyl benzoate esters to form alkenes by freshly prepared, highly activated titanium metal is presented. Utilization of the alkylating agent !-(chloromethyl)-ethenyl diethyl phosphate with ketones is developed. Cyclopentenone formation either via alkylation, hydrolysis, and cyclization or directly from alkylated ketones under mild basic conditions is described.
dc.description.departmentChemistry, Department of
dc.format.digitalOriginreformatted digital
dc.format.mimetypeapplication/pdf
dc.identifier.other10289079
dc.identifier.urihttps://hdl.handle.net/10657/15583
dc.language.isoen
dc.rightsThis item is protected by copyright but is made available here under a claim of fair use (17 U.S.C. Section 107) for non-profit research and educational purposes. Users of this work assume the responsibility for determining copyright status prior to reusing, publishing, or reproducing this item for purposes other than what is allowed by fair use or other copyright exemptions. Any reuse of this item in excess of fair use or other copyright exemptions requires express permission of the copyright holder.
dc.subjectOrganic compounds--Synthesis
dc.subjectBenzoates
dc.subjectEsters
dc.subjectCyclopentenone
dc.title1. Reduction of phenylthiomethylcarbinyl benzoate esters to alkenes with titanium metal. 2. Cyclopentenone synthesis via the alkylating agent 1-(chloromethyl) ethenyl diethyl phosphate
dc.type.dcmiText
dc.type.genreThesis
dcterms.accessRightsThe full text of this item is not available at this time because it contains documents that are presumed to be under copyright and are accessible only to users who have an active CougarNet ID. This item will continue to be made available through interlibrary loan.
thesis.degree.collegeCollege of Natural Sciences and Mathematics
thesis.degree.departmentChemistry, Department of
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Houston
thesis.degree.levelDoctoral
thesis.degree.nameDoctor of Philosophy

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