Hg(6[raised 1]P[lowered 1]) photosensitized reactions of ethylene

dc.contributor.committeeMemberZlatkis, Albert
dc.contributor.committeeMemberBecker, Ralph S.
dc.contributor.committeeMemberBrand, Louis
dc.contributor.committeeMemberWentworth, Wayne E.
dc.creatorRuland, Norman Lee
dc.date.accessioned2022-06-22T20:15:53Z
dc.date.available2022-06-22T20:15:53Z
dc.date.issued1967
dc.description.abstractAn experimental system for the study of Hg(6[raised 1]P[lowered 1]) photosensitized reactions was developed. Ethylene decomposition was carried out over a pressure range from 10 to 130 torr with illumination times of ten and twenty minutes. Major products found were C[lowered 2]H[lowered 2], H[lowered 2], n-C[lowered 4]H[lowered 10], C[lowered 2]H[lowered 6], 1-C[lowered 4]H[lowered 8], C[lowered 3]H[lowered 8], and C[lowered 3]H[lowered 6]. No methane was observed. Decrease in product yields at higher ethylene pressures indicated that an excited state of ethylene was formed prior to decomposition. On the basis of earlier studies and the observed product distributions it was concluded that three major primary processes occurred:...
dc.description.departmentChemistry, Department of
dc.format.digitalOriginreformatted digital
dc.format.mimetypeapplication/pdf
dc.identifier.other13737375
dc.identifier.urihttps://hdl.handle.net/10657/9937
dc.language.isoen
dc.rightsThis item is protected by copyright but is made available here under a claim of fair use (17 U.S.C. Section 107) for non-profit research and educational purposes. Users of this work assume the responsibility for determining copyright status prior to reusing, publishing, or reproducing this item for purposes other than what is allowed by fair use or other copyright exemptions. Any reuse of this item in excess of fair use or other copyright exemptions requires express permission of the copyright holder.
dc.titleHg(6[raised 1]P[lowered 1]) photosensitized reactions of ethylene
dc.type.dcmiText
dc.type.genreThesis
thesis.degree.collegeCollege of Arts and Sciences
thesis.degree.departmentChemistry, Department of
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Houston
thesis.degree.levelDoctoral
thesis.degree.nameDoctor of Philosophy

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