A total synthesis of ([plus-minus])-trans-chrysanthemic acid

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dc.contributor.advisorWelch, Steven C.
dc.contributor.committeeMemberKimball, Aubrey P.
dc.creatorValdes, Theresa Ann
dc.date.accessioned2022-02-14T20:09:53Z
dc.date.available2022-02-14T20:09:53Z
dc.date.issued1976
dc.description.abstractThe total synthesis of ([plus-minus])-trans-chrysanthemic acid (1) from eucarvone (66) via intermediate [delta][cubed]-4-methylcaren-5-one (68)is discussed. The present synthetic scheme proceeds by ozonolysis of carenone 68 to a key intermediate, keto-acetal 73. Reductive elimination of the enol diethyl phosphate of acetal 73 leads to olefin aldehyde 58 which is ultimately oxidized to ([plus-minus])-trans-chrysanthemic acid.
dc.description.departmentChemistry, Department of
dc.format.digitalOriginreformatted digital
dc.format.mimetypeapplication/pdf
dc.identifier.other3718048
dc.identifier.urihttps://hdl.handle.net/10657/8820
dc.language.isoen
dc.rightsThis item is protected by copyright but is made available here under a claim of fair use (17 U.S.C. §107) for non-profit research and educational purposes. Users of this work assume the responsibility for determining copyright status prior to reusing, publishing, or reproducing this item for purposes other than what is allowed by fair use or other copyright exemptions. Any reuse of this item in excess of fair use or other copyright exemptions requires express permission of the copyright holder.
dc.titleA total synthesis of ([plus-minus])-trans-chrysanthemic acid
dc.type.dcmiText
dc.type.genreThesis
thesis.degree.collegeCollege of Natural Sciences and Mathematics
thesis.degree.departmentChemistry, Department of
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Houston
thesis.degree.levelDoctoral
thesis.degree.nameDoctor of Philosophy

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