Browsing by Author "Schmid, Steven Robert"
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Item An experimental investigation of chlorine''s action on Pinene and optimization for 2,6-dichlorocamphane(1977) Schmid, Steven Robert; Willcott, M. R.; Deming, Stanley N.Optimization for 2,6-dichlorocamphane from continuous flow reactions of chlorine with [proportional to]-pinene was accomplished using the simplex algorithm of Spendley, Hext, and Himsworth, as modified by Nelder and Mead. The yields (20-25%) obtained were 3.5 times greater than the best value previously reported in the literature. A central composite design study revealed that a second-order polynomial was not a good approximation for the response surface in carbon tetrachloride. The mole ratio of chlorine to [proportional to]-pinene appeared to have some impact on determining the yield of 2,6-dichlorocamphane, especially when the ratio was less than or approximately equal to one.