Browsing by Author "Barnes, Garland R."
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Item The reactions and kinetics of rhodium(II) acetate with carboxylic acids(1970) Barnes, Garland R.; Bear, John L.; Willcott, Mark Robert, III; Geanangel, Russell A.; Kimball, Aubrey P.The reaction of rhodium(II) acetate with excess carboxylic acids were followed by nuclear magnetic resonance spectroscopy. The reaction was found to be a stepwise exchange of deuteroacetate for the acetate cage. The rate constants measured have a ratio of approximately 1:0.75:0.5:0.25 for k[lowered 1]:k[lowered 2]:k[lowered 3]:k[lowered 4]. The ratio is due to a statistical effect depending on the number of "exchange" sites available on the reaction species.