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dc.contributor.advisorLubchenko, Vassiliy
dc.creatorBevzenko, Dmytro 1981-
dc.date.accessioned2015-08-25T00:00:49Z
dc.date.available2015-08-25T00:00:49Z
dc.date.createdAugust 2013
dc.date.issued2013-08
dc.identifier.urihttp://hdl.handle.net/10657/1048
dc.description.abstractEssential microscopic aspects of activated transport in liquids, which precedes the glass transition, have evaded explanation for decades. These poorly understood aspects include: the molecular underpinning of the excess, configurational entropy; the transition state configurations for the activated transport; the chemical origin of the fragile vs. strong liquid behavior; and many others. This dissertation puts forth a radically novel way to address these open questions, in which liquids near their glass transition are viewed as structurally degenerate assemblies of strongly interacting, local sources of frozen-in stress. The thermodynamics and activated barriers for rearrangement of this stress field have been mapped onto a Heisenberg model with six-dimensional spins. A meanfield analysis of the spin model has shown glasses can be viewed as frozen-in patterns of shear stress and/or uniform compression/dilation, the two extremes corresponding to the strong and fragile behaviors. A self-consistent elasticity theory of aperiodic, metastable solids emerges in the present analysis; it supersedes the traditional elasticity theory, which fails to self-consistently account for the structural degeneracy stemming from the inherent mismatch between cohesive forces and steric repulsion. The observable elastic constants self-consistently emerge in theory similarly to how the dielectric susceptibility is determined by the properties of molecular dipoles. First simulations of the spin model have been carried out. In addition to direct observations of transition states for the activated transport, several key features of the glass transition are yielded by the spin model, including a strongly non-exponential, non-Arrhenius character of the relaxations and its correlation with the Poisson ratio of the substance.
dc.format.mimetypeapplication/pdf
dc.language.isoeng
dc.subjectamorphous solids
dc.subjectglass
dc.subjectsupercooled liquids
dc.subjectstructural entropy
dc.subjectEshelby tensor
dc.subjectinhomogeneous inhomogeneity
dc.subjectconfigurational entropy
dc.subjecttemperature exchange Monte Carlo
dc.subjectactivated transport
dc.subjectcavity method
dc.subjectpolar liquid
dc.subject.lcshChemistry
dc.titleSelf-consistent theory and structural dynamics of equilibrium aperiodic solids
dc.date.updated2015-08-25T00:00:49Z
dc.type.genreThesis
thesis.degree.nameDoctor of Philosophy
thesis.degree.levelDoctoral
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Houston
thesis.degree.departmentChemistry
dc.contributor.committeeMemberBittner, Eric R.
dc.contributor.committeeMemberKouri, Donald J.
dc.contributor.committeeMemberCai, Chengzhi
dc.contributor.committeeMemberVekilov, Peter G.
dc.type.dcmiText
dc.format.digitalOriginborn digital
dc.description.departmentChemistry
thesis.degree.collegeCollege of Natural Sciences and Mathematics


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