A stereoselective synthesis of ([plus-minus])-methyl jasmonate

dc.contributor.advisorWelch, Steven C.
dc.contributor.committeeMemberZlatkis, Albert
dc.creatorChu, Ping Sun
dc.date.accessioned2022-02-14T19:34:58Z
dc.date.available2022-02-14T19:34:58Z
dc.date.issued1976
dc.description.abstractA short convergent synthesis of (+)-methyl jasmonate(l) is presented. The key step involves a nucleophilic B-alkylation, then an electrophilic a-alkylation on enone 6. The reaction is highly stereoselective and regioselective. Methyl dehydrojasmonate (7), an immediate precursor of methyl jasmonate(l)was obtained by cleavage of the ketotriester 11 in one step.
dc.description.departmentChemistry, Department of
dc.format.digitalOriginreformatted digital
dc.format.mimetypeapplication/pdf
dc.identifier.other3064355
dc.identifier.urihttps://hdl.handle.net/10657/8809
dc.language.isoen
dc.rightsThis item is protected by copyright but is made available here under a claim of fair use (17 U.S.C. §107) for non-profit research and educational purposes. Users of this work assume the responsibility for determining copyright status prior to reusing, publishing, or reproducing this item for purposes other than what is allowed by fair use or other copyright exemptions. Any reuse of this item in excess of fair use or other copyright exemptions requires express permission of the copyright holder.
dc.titleA stereoselective synthesis of ([plus-minus])-methyl jasmonate
dc.type.dcmiText
dc.type.genreThesis
thesis.degree.collegeCollege of Arts and Sciences
thesis.degree.departmentChemistry, Department of
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Houston
thesis.degree.levelMasters
thesis.degree.nameMaster of Science

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