Solid-solid and solid-gas thermal reactions of some cobalt (III) ammine complexes

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1969

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Abstract

The cis-dichloro-complex is the product of thermal deaquation from the corresponding diaquo-complex. Examples are show in the following equations: (Co(NH[lowered 5])[lowered 4](H[lowered 2]O)[lowered 2])Cl[lowered 5]--->cis-(Co(NH[lowered 3])[lowered 4]Cl[lowered 2])Cl (Co(en)[lowered 2](H[lowered 2]O)[lowered 2])Cl[lowered 3][dot]2H[lowered 2]O--->cis-(Co(en)[lowered 2]Cl[lowered 2])Cl . The trans-dichloro-complex is the product from the thermal matriz reaction of the corresponding complex-nitrate with ammonium chloride. A proton plays an important role in this reaction...

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