Mechanisms for the thermal deamination of some tris(ethylenediamine)cobalt(III) complexes

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dc.contributor.advisorWendlandt, W. W.
dc.contributor.committeeMemberBear, John L.
dc.contributor.committeeMemberWood, Lowell T.
dc.contributor.committeeMemberGeanangel, Russell A.
dc.contributor.committeeMemberVeillon, Claude
dc.creatorCollins, Louis Wayne
dc.date.accessioned2022-01-25T16:32:50Z
dc.date.available2022-01-25T16:32:50Z
dc.date.issued1973
dc.description.abstractThe thermal decomposition of tris(ethylenediamine)cobalt(III) complexes was investigated through the use of thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermomagnetic analysis, infrared spectroscopy, reflectance spectroscopy, mass spectroscopy, and evolved gas analysis. Data were collected, compiled, and analyzed in order to determine the thermal decomposition mechanism for the complexes. Intermediates were identified for the chloride, bromide, iodide, thiocyanate, nitrate and bisulfate complexes. Some of the thermal data were explained in terms of the kinetics of the mechanism steps.
dc.description.departmentChemistry, Department of
dc.format.digitalOriginreformatted digital
dc.format.mimetypeapplication/pdf
dc.identifier.other13720180
dc.identifier.urihttps://hdl.handle.net/10657/8541
dc.language.isoen
dc.rightsThis item is protected by copyright but is made available here under a claim of fair use (17 U.S.C. §107) for non-profit research and educational purposes. Users of this work assume the responsibility for determining copyright status prior to reusing, publishing, or reproducing this item for purposes other than what is allowed by fair use or other copyright exemptions. Any reuse of this item in excess of fair use or other copyright exemptions requires express permission of the copyright holder.
dc.titleMechanisms for the thermal deamination of some tris(ethylenediamine)cobalt(III) complexes
dc.type.dcmiText
dc.type.genreThesis
thesis.degree.collegeCollege of Arts and Sciences
thesis.degree.departmentChemistry, Department of
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Houston
thesis.degree.levelDoctoral
thesis.degree.nameDoctor of Philosophy

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