Studies of fluxional organometallic compounds with 1H and 13C NMR Fourier transform spectroscopy

dc.contributor.committeeMemberAlbright, Thomas A.
dc.contributor.committeeMemberKohn, Harold Lewis
dc.contributor.committeeMemberThummel, Randolph Paul
dc.contributor.committeeMemberGeanangel, Russell A.
dc.contributor.committeeMemberTu, Shiao-Chun
dc.creatorSeiglie, Carlos A.
dc.description.abstractThe purpose of the investigation is to determine the fluxionality in (n4-C8H12)Fe(C0)3 and (n4-C7H8)Cr(C0)4 using the Fourier transform spectrometer. We develop models for two, three and four site exchange applicable in determining the mechanism of exchange in fluxional penta-coordinate organometallic compounds using selective excitation. Selective excitation has been accurately applied experimentally and theoretically and we present an approach which explains the problems of the technique. We apply selective excitation and spin saturation transfer using a Varian FT-80 and XL-1OO Fourier transform spectrometers using 13C and 1H spectrometery. [...]
dc.description.departmentChemistry, Department of
dc.format.digitalOriginreformatted digital
dc.rightsThis item is protected by copyright but is made available here under a claim of fair use (17 U.S.C. Section 107) for non-profit research and educational purposes. Users of this work assume the responsibility for determining copyright status prior to reusing, publishing, or reproducing this item for purposes other than what is allowed by fair use or other copyright exemptions. Any reuse of this item in excess of fair use or other copyright exemptions requires express permission of the copyright holder.
dc.subjectOrganometallic compounds--Spectra
dc.subjectFourier transform spectroscopy
dc.titleStudies of fluxional organometallic compounds with 1H and 13C NMR Fourier transform spectroscopy
dc.type.genreThesis of Natural Sciences and Mathematics, Department of of Houston of Science


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