Stopped flow kinetic investigations of metalloporphyrin redox reactions and electrochemistry in nonaqueous solvents

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dc.contributor.advisorKadish, Karl M.
dc.contributor.committeeMemberDeming, Stanley N.
dc.contributor.committeeMemberWendlandt, Wesley W.
dc.contributor.committeeMemberGeanangel, Russell A.
dc.contributor.committeeMemberTu, Shiao-Chun
dc.creatorDing, Jianquan
dc.date.accessioned2024-01-24T17:20:33Z
dc.date.available2024-01-24T17:20:33Z
dc.date.issued1985
dc.description.abstractStopped flow kinetics were used for investigating the oxidation or reduction of various metalloporphyrins. The kinetics for oxidation of five different (p-X)TPPAg(II) complexes were measured using ceric sulfate as an oxidant while the kinetics for reduction of TPPMnCl and TPPFeCl were measured using ascorbic acid. Kinetics were also measured for oxidation of TPPCo(Il) using hydrogen peroxide. All of these reactions were carried out in DMSO and spectrophotometric monitoring was via a Tracor Northern Rapid Scanning Spectrophotometer. [...]
dc.description.departmentChemistry, Department of
dc.format.digitalOriginreformatted digital
dc.format.mimetypeapplication/pdf
dc.identifier.other14253605
dc.identifier.urihttps://hdl.handle.net/10657/16067
dc.language.isoen
dc.rightsThis item is protected by copyright but is made available here under a claim of fair use (17 U.S.C. Section 107) for non-profit research and educational purposes. Users of this work assume the responsibility for determining copyright status prior to reusing, publishing, or reproducing this item for purposes other than what is allowed by fair use or other copyright exemptions. Any reuse of this item in excess of fair use or other copyright exemptions requires express permission of the copyright holder.
dc.subjectPorphyrins
dc.titleStopped flow kinetic investigations of metalloporphyrin redox reactions and electrochemistry in nonaqueous solvents
dc.type.dcmiText
dc.type.genreThesis
thesis.degree.collegeCollege of Natural Sciences and Mathematics
thesis.degree.departmentChemistry, Department of
thesis.degree.disciplineChemistry
thesis.degree.grantorUniversity of Houston
thesis.degree.levelDoctoral
thesis.degree.nameDoctor of Philosophy

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